Bis[(4-chlorobenzyl)triphenylphosphonium] tetrachloridozincate(II) trihydrate
نویسندگان
چکیده
The crystal structure of the title compound, (C(25)H(21)ClP)(2)[ZnCl(4)]·3H(2)O, consists of tetra-hedral phosphonium cations and tetra-hedral zincate anions; the water mol-ecules form weak hydrogen bonds to the anions. Two of the water mol-ecules are disordered over three sites in a 0.68:0.55:0.77 ratio.
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The asymmetric unit of the title compound, (C(8)H(11)N(2)S)(2)[ZnCl(4)], contains two S-benzyl-isothio-uronium cations which differ in the C-C-S-C torsion angle [165.3 (2) and 81.9 (2)°] and a tetrahedral tetra-chloridozincate anion. The crystal structure is stabilized by N-H⋯Cl, C-H⋯Cl and C-H⋯S inter-actions.
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